Thirty minutes before the Golden Globes began, Brad Pitt and Angelina Jolie arrived on the red carpet Sunday. She was spotted fixing Pitt's bow tie as they stepped on to the carpet.Jolie - who dodged E!'s Ryan Seacrest when he tried to approach her for an interview with Pitt - wore an Atelier Versace gown, Platinum by Neil Lane jewelery and Jimmy Choo shoes.
Pitt is nominated for his leading dramatic role in The Curious Case of Benjamin Button, while Jolie is up for her leading dramatic role in Changeling.
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